Cesa Stat Antistatic Additives - Standard Portfolio POLYMER FAMILY MATERIAL PRODUCT NAME DOSAGE Polyolefin PEATEC Cesa Stat PEATEC 1.0–4.0% Polypropylene PPA0820051 Cesa Stat PPA0820051 1.0–4.0% Polyamide ABAN698400 Cesa Stat 99027 5.0–15.0% Polyester NBAN698440 Cesa Stat 3526 2.5–10.0% Polycarbonate NCA0820011 Cesa Stat NCA0820011 5.0–8.0% Styrenic SLAN698401 Cesa Stat 3301 3.0–7.5% TPU RUA0820024 Cesa Stat RUA0820024 2.0–4.0% Polyester FPA1660283 Hiformer™ liquid additives for polyolefins 0.10–0.50% Cesa Stat Antistatic Additives can be used in combination with other Cesa masterbatches, and formulations can be customized for most applications.

Rigid thermoplastics include both commodity thermoplastics and engineering thermoplastics, such as polypropylene (PP), polystyrene (PS), high impact polystyrene (HIPS), polycarbonate (PC), acrynitrile-butadiene-styrene (ABS), poly(ethylene terephthalate) (PET), poly(methylmethacrylate) (PMMA), styrene acrylonitrile (SAN), poly(phenylene oxide) (PPO), polyamide (PA), PC/ABS blend and PPO/PS blend etc.. Figure 1 Surface energy of various thermoplastic elastomers with rigid thermoplastics Engineering Plastics Polyamide 6,6 ABS Polycarbonate Acrylic Polystyrene Polypropylene Polyethylene Elastomers COPA TPU COPE S-TPE TPV mPE Surface Energy (mN/m) 46 43 40 37 34 31 28 Figure 2 Schematic diagram of the peel test Table I Physical property of TPE-1 Shore A Hardness (10 second delay) 44 Specific Gravity (g/cm3) 0.90 Color Natural 300 % Modulus (PSI) 348 Tensile Strength (PSI) 603 Elongation at Break (%) 598 Tear Strength (lbf/in) 110 Table II Adhesion value of TPE-1 on different substrates Substrate Average Peel Strength (lbf) Failure Type PP 17 Cohesive Copolyester 13 Adhesive PET 13 Adhesive PPE/HIPS 18 Adhesive PMMA 15 Adhesive PS 18 Adhesive PC 17 Adhesive PC/ABS 14 Adhesive HIPS 13 Adhesive ABS 13 Adhesive Table III Properties and peel strength of TPE-2 materials 15.37Nylon 11.16.5POM 227Polyester 22.619PC/ABS 24.5-ABS 20.828PP Peel Strength (PIL) 713721Tensile Elongation (%): 10811010Tensile Strength (psi): 5651Hardness: BA 15.37Nylon 11.16.5POM 227Polyester 22.619PC/ABS 24.5-ABS 20.828PP Peel Strength (PIL) 713721Tensile Elongation (%): 10811010Tensile Strength (psi): 5651Hardness: BA Figure 3 Capillary viscosity of TPE-1 and -2 at 200°C 1.00E+00 1.00E+01 1.00E+02 1.00E+03 1.00E+01 1.00E+02 1.00E+03 1.00E+04 1.00E+05 Shear rate (1/sec) V is co si ty ( P a* se c) TPE-1 TPE-2A TPE-2B GLS Corporation Abstract Introduction Experimental Material Two classes of “universal overmolding TPEs” have been developed and used in this study.

Specialized chemistries enable TPEs to adhere to many different plastic substrates, including PP, polycarbonate (PC), acrylonitrile-butadiene-styrene (ABS), PC/ABS, copolyester, polyamide, and polystyrene.

The focus for this study was to develop thermoplastic elastomer compounds that would overmold onto substrates made from Nylon (PA), Polycarbonate (PC), Acrylonitrile-butadiene-styrene (ABS), and PC/ABS alloys

POLYMER FAMILY MATERIAL PRODUCT NAME PRODUCT TYPE DOSAGE Polyolefin PEAN698413 CESA Antimicro SE 99-58 Silver 2–7.5% Polyolefin PEAN698432 CESA Antimicro J8146 Zinc 1–4% Polypropylene PPA0698636 CESA Antimicro J8259 Zinc 1–4% Nylon ABA0820032 CESA Antimicro ABA0820032 Silver 2–7.5% Polyester NBAN698441 CESA Antimicro S58441 Silver 2–7.5% Polycarbonate NCAN820009 CESA Antimicro NCAN820009 Silver 2–7.5% TPU RUA0698433 CESA Antimicro J8843 Zinc 1–4% Styrenic SLA0820011 CESA Antimicro SLA0820011 Zinc 1–4%

Thermoplastics used in making composites range from polypropylene (PP), nylon (PA) and polycarbonate (PC) to polyester, polyphenylene sulfide (PPS), and polyetheretherketone (PEEK).

KEY CHARACTERISTICS • Manufactured at four ISO 13485 certified sites, providing global consistency and increased security of supply • Documented change control beyond CAS number reducing risk of change • Non-phthalate and formulated without animal- derived substances • Available for use in a wide range of polymers including polyolefins, styrenics, polycarbonate and alloys, polyester, POM • Functionality can be combined with colorants into convenient combination concentrates and ready-to-use formulations REGULATORY SUPPORT • Raw materials tested to: - ISO 10993-1 and USP biological evaluation - European Pharmacopeia 3.1.3/3.1.5 (polyolefin) - USP (polyethylene) - ICH Q3D elemental impurities • Registered Drug Master File (Type III) and/or Device Master File • Food contact established with FDA/EU* APPLICATION BULLETIN * FDA/EU compliance information available upon request FUNCTIONALITY TARGET APPLICATIONS DRUG DELIVERY DEVICES SYRINGES & NEEDLES DIAGNOSTICS CATHETERS Clarifying PP Sorbitol-free for transparent applications with reduced migration and improved thermal stability     Lubricant— permanent/ non-migrating Fast acting reduction in friction for wide variety of polymers such as PP, ABS, POM, PC    Protection from UV in transparent applications for PP, PE, PETG, COP UV blocking in 290-450nm with no impact on clarity; can be combined with colors (e.g., amber)   Antistatic ready-to- use solution for PP, ABS, PC/ABS Permanent/non-migrating; fast decay time independent of % relative humidity  Gamma/e-beam sterilization protection of the polymer Preserving the properties of PP and COC/COP; reduction in yellowing using Color Compensation Technology (CCT)    Reduced material consumption/cycle time—nucleation Fast acting new generation nucleant for PE and PP; improved thermal and mechanical properties allows wall thinning; reduction of tolerance/dimensional problems between different colors    Laser marking replacing ink printing/labels Solvent-free, high-speed identification for Nd/YAG laser for PE,PP, ABS, PC, POM     Antioxidants for PE, PP, TPE Thermal protection during converting/downstream sterilization    Brand protection/ anticounterfeit Covert and non-covert systems   Healthcare use limitations apply—see below.

KEY CHARACTERISTICS • Manufactured at four ISO 13485 certified sites, providing global consistency and increased security of supply • Documented change control beyond CAS number, reducing risk of change • Non-phthalate and formulated without animal- derived substances • Available for use in a wide range of polymers including polyolefins, styrenics, polycarbonate and alloys, polyester, POM • Functionality can be combined with colorants into convenient combination concentrates or formulations REGULATORY SUPPORT • Pre-tested raw materials: - ISO 10993-1 and USP biological evaluation - European Pharmacopeia 3.1.3/3.1.5 (polyolefin) - USP (polyethylene) - ICH Q3D elemental impurities • Registered Drug Master File (Type III) • Food contact established with FDA/EU* APPLICATION BULLETIN * FDA/EU compliance information available upon request FUNCTIONALITY TARGET APPLICATIONS EBM/IBM CONTAINERS CLOSURES FILM COMBINATION DEVICES Clarifying PP Sorbitol-free—possibilities in packaging ocular solutions    Slip/torque reduction Slip for PE, PP films, processing aid, torque reduction for closures   Protection from UV in transparent packaging for PP, PE, PETG, COP UV blocking in 290–450nm with no impact on clarity    Antistatic ready-to-use solution for PE films e.g.

When overmolded, GLS TPEs bond permanently and seamlessly to many different plastic substrates, including polypropylene (PP), polycarbonate (PC), acrylonitrile-butadiene- styrene (ABS), PC/ABS, copolyester, polyamide (nylon) and polystyrene (PS).

More design options TPEs have excellent overmold adhesion to common polycarbonate substrates, opening up the opportunity to add interesting features that you may not be able to achieve with silicone.