PolyOne Corporation Investor Day 2012 PolyOne Investor Presentation Credit Suisse 26th Annual Chemical and Ag Science Conference September 17th, 2013 • In this presentation, statements that are not reported financial results or other historical information are “forward-looking statements” within the meaning of the Private Securities Litigation Reform Act of 1995. Net debt $ 638.8 Adjusted EBITDA Q3 2012 Q4 2012 Q1 2013 Q2 2013 Total PolyOne Income before income taxes $ 30.6 $ (1.1) $ 15.7 $ 62.9 $ 108.1 PolyOne Interest expense, net 12.4 13.7 15.6 16.6 58.3 PolyOne Depreciation and amortization 17.0 15.5 19.0 25.8 77.3 PolyOne Special items in EBITDA 8.3 26.5 27.7 (5.2) 57.3 PolyOne Adjusted EBITDA 68.3 54.6 78.0 100.1 301.0 Pro forma Spartech EBITDA 16.8 14.7 11.2 - 42.7 Pro forma EBITDA $ 85.1 $ 69.3 $ 89.2 $ 100.1 $ 343.7 PolyOne Investor Presentation�Credit Suisse 26th Annual Chemical and Ag Science Conference��September 17th, 2013� Forward – Looking Statements Use of Non-GAAP Measures Strategy and Execution Drive Results Four Pillar Strategy PolyOne�At A Glance Mix Shift Highlights Specialty Transformation Proof of Performance & 2015 Goals Innovation Drives Earnings Growth We are Experts in Polymer Science and Formulation Positioned for Strong Growth First Half 2013 Financial Highlights Debt Maturities & Liquidity Summary – 6/30/13 Use of Cash Why Invest In PolyOne?

KEY CHARACTERISTICS • Lightweight • High strength & stiffness • Excellent fatigue & impact resistance • Exceptional strength-to-weight ratio • Strong adhesive properties • Chemical and corrosion resistance • Reduced NVH compared to metals • Rapid cycle times • Low VOCs VALUE SOLUTION • Replaces metal without sacrificing strength • Reduced vehicle weight improves fuel economy, reduces energy consumption • Selective reinforcement adds strength in high stress areas • Easily integrated & streamlined manufacturing process • Easy bonding to various materials • Increases structure & puncture resistance • Can be used in injection and compression overmolding operations • Enables thin-walling and material reduction by adding reinforcement to traditional materials • Able to be re-formed, reused, recycled USES & APPLICATIONS • Interior structural reinforcement such as walls, load floors, headliners, door panels, storage, storage lids, and trim pieces • External body panels • Front end and door module reinforcement • Service access cover reinforcement • Interior hatch covers GORDON COMPOSITES™ & GLASFORMS™ THERMOSET COMPOSITES Gordon Composites™ and Glasforms™ thermoset composites are made with proprietary resin/ fiber reinforcement technologies.

BENEFITS OF VERSAFLEX PF FOR SURFACE PROTECTIVE FILMS: • Customizable tack • Single-step manufacturing process (co- extrusion) • Low volatile organic compound (VOC) emissions during manufacturing • Eliminates secondary coating and drying operations • Eliminates hazardous liquid chemicals compared to solvent systems • Reduces converting costs versus coating • Reduces energy consumption MARKETS AND APPLICATIONS Versaflex PF formulations, customizable based on desired level of tack, are co-extruded with protective films to provide just the right amount of protection during the fabrication, assembly, shipment, storage and installation of finished goods in many industries and end-use applications including: • Optical films and display panels for consumer electronics • Home appliances • Construction and building materials • Furniture and cabinetry • Automotive and other transportation 100/0 90/10 80/20 70/30 60/40 40/60 30/70 20/80 10/90 0/100 0.9 1.1 2.0 2.4 2.8 3.7 3.8 4.9 0 1 2 3 4 5 6 7 8 6.5 1.6 MD6727 MD6748 MD6700 MD6666 9512 MD6649 MD6741 0 2 4 6 8 10 12 % of MD6741/MD6700 Degree of tack can be customized for substrate surfaces.

RC 14001®:2023 O RC 14001® é uma norma que combina a certificação ISO 14001 com requisitos adicionais para o Chemical Responsible Care Management System® (RCMS), incluindo saúde e segurança, transporte, divulgação, resposta a emergências e muito mais.

Francisco Nakasato, Bairro São Roque das Chaves 1700 Itupeva SP 13295-000 Brazil Avient Belgium SA Design and manufacture of color and additive concentrates, thermoplastic resins and specialty compounds Rue Melville Wilson 2, B-5330 Assesse, Belgium Magna Colours Limited The design, manufacture and distribution of specialty colouration products and chemical auxiliaries for us in the textile, dying, printing and finishing industries.

Chemical Mfg. Regulations related to chemicals are also evolving globally. Many other countries are following suit on the EU REACH chemicals regulation or a similar framework.

General Manager, Nalco Chemical Company Europe (a manufacturer of specialty chemicals, services and systems) from April 2006 to March 2008. President, Specialty & Fine Chemicals — Cambrex Corporation (a specialty chemical and pharmaceutical business) from August 1994 to November 2000. The S&P Mid Cap Chemicals index includes a broad range of chemical manufacturers.

General Manager Nalco Chemical Company Europe (a manufacturer of specialty chemicals, services and systems) from April 2006 to March 2008. President, Specialty & Fine Chemicals — Cambrex Corporation (a specialty chemical and pharmaceutical business) August 1994 to November 2000. The S&P Mid Cap Chemicals index includes a broad range of chemical manufacturers.

PolyOne Stock Performance The following is a graph that compares the cumulative total shareholder returns for PolyOne’s common shares, the S&P 500 index and the S&P Mid Cap Chemicals index, with dividends assumed to be reinvested when received. The S&P Mid Cap Chemicals index includes a broad range of chemical manufacturers. Because of the relationship of PolyOne’s business within the chemical industry, comparison with this broader index is appropriate.

Artisan™ AR7300 PRE-COLORED FORMULATIONS PROCESSING GUIDE Artisan™ Pre-Colored Thermoplastics Artisan™ AR7300 pre-colored thermoplastics are customized ABS formulations to help manufacturers achieve brilliant and high-gloss metallic effect, excellent chemical resistance, and scratch resistance.