USE OF NON-GAAP MEASURES PolyOne Corporation 3 • This presentation includes the use of both GAAP (generally accepted accounting principles) and non-GAAP financial measures. PolyOne’s chief operating decision maker uses these financial measures to monitor and evaluate the ongoing performance of the Company and each business segment and to allocate resources. In addition, operating income before special items and adjusted EPS are components of various PolyOne annual and long-term employee incentive plans

Water Street North Baltimore, OH 45872 Activity: Design and Manufacture of Colour and Additive Concentrates, Activity: Design and Manufacture of Custom PVC Plastisol and PVC Slush Mold Powder Facility: Avient Corporation - Malmö, Sweden Järnyxegatan 7 P.O.

Water Street North Baltimore, OH 45872 Activity: Manufacture of Colour and Additive Concentrates, Thermoplastic Resins and Specialty Compounds Activity: Design and Manufacture of Custom PVC Plastisol and PVC Slush Mold Powder Facility: Avient Corporation - Malmö, Sweden Järnyxegatan 7 P.O.

Water Street North Baltimore, OH 45872 Activity: Design and Manufacture of Colour and Additive Concentrates, Activity: Design and Manufacture of Custom PVC Plastisol and PVC Slush Mold Powder Facility: Avient Corporation - Malmö, Sweden Järnyxegatan 7 P.O.

Massillon, OH 44646 Phone: 1.330.834.3820 Fax: 1.330.837.8467 EUROPE PolyOne Belgium SA Rue Melville Wilson 2 5330 Assesse Belgium Phone: +32 (0) 83 660 271 E-mail: info.color@polyone.com ASIA PolyOne Shanghai China No. 88, GuoShouJing Road Z.J. We believe no competitor can match our technical expertise because no workforce can outperform the people of PolyOne. Massillon, OH 44646 Phone: 1.330.834.3820 Fax: 1.330.837.8467 EUROPE PolyOne Belgium SA Rue Melville Wilson 2 5330 Assesse Belgium Phone: +32 (0) 83 660 271 E-mail: info.color@polyone.com ASIA PolyOne Shanghai China No. 88, GuoShouJing Road Z.J.

Slide 1 PolyOne Corporation Page 1 PolyOne Investor Presentation Goldman Sachs 2014 US Emerging / SMID Cap Growth Conference New York, NY November 20, 2014 PolyOne Corporation Page 2 Forward-Looking Statements  In this presentation, statements that are not reported financial results or other historical information are “forward-looking statements” within the meaning of the Private Securities Litigation Reform Act of 1995. In addition, operating income before special items and adjusted EPS are components of various PolyOne annual and long-term employee incentive plans ��PolyOne Investor Presentation�Goldman Sachs 2014 US Emerging / SMID Cap Growth Conference�New York, NY�November 20, 2014�� Forward-Looking Statements Use of Non-GAAP Measures PolyOne Commodity to Specialty Transformation PolyOne�At A Glance Mix Shift Highlights Specialty Transformation Confirmation of Our Strategy Strategy and Execution Drive Results Proof of Performance & 2015 Goals 32% Adjusted EPS CAGR from 2011 Innovation Drives Earnings Growth A Rich Pipeline of Opportunity Megatrends Aligned with Key End Markets Debt Maturities & Pension Funding – 9/30/14 Free Cash Flow and Strong Balance Sheet �Fund Investment / Shareholder Return PolyOne Core Values Why Invest In PolyOne?