https://www.avient.com/news/avient-brings-sustainable-innovation-npe-2024
Cesa™ Non-PFAS Process Aid for Extrusion: for use in polyethylene (PE) and polypropylene (PP) applications, it reduces friction between the polymer and the metal during extrusion comparable to a traditional processing aid but is formulated without fluoropolymers which may be classifiable as per- and polyfluorinated substances (PFAS) and will be presented during Avient’s technical seminar at NPE, “PFAS Alternatives: 2024 and Beyond,” by Sean Bernhardt, Senior Research and Development Manager, Color, Additives, & Inks, Americas at Avient, on May 7 at 3 p.m. and May 8 at 1 p.m.
Lightweighting Applications: Exploring the potential of foaming techniques and polymer substitutions to reduce weight and enhance efficiency, thus replacing traditional metal components
https://www.avient.com/sites/default/files/2020-10/2020-gravi-tech-design-guide-.pdf
Base Resin ABS PA PBT PC PE PEEK PP PPS
Barrel Temperatures °F (°C)
Rear Zone 400–475(200–250)
480–540
(248–282)
480–520
(250–270)
480–570
(250–300)
400–445
(200–230)
660–700
(350–475)
400–440
(200–225)
520–600
(270–300)
Center Zone 410–480(205–253)
490–550
(254–287)
485–525
(251–273)
500–580
(260–305)
410–455
(207–237)
670–710
(357–385)
410–450
(205–230)
550–610
(285–310)
Front Zone 420–490(210–257)
500–560
(260–293)
490–530
(254–276)
515–590
(267–310)
420–465
(213–243)
680–720
(363–400)
420–455
(215–235)
570–620
(300–320)
Nozzle 425–500(215–260)
510–570
(265–298)
490–540
(254–282)
530–600
(275–315)
430–475
(220–250)
700–730
(370–395)
430–460
(220–240)
610–620
(320–325)
Melt Temperature 425–515(215–270)
510–570
(265–298)
490–540
(254–282)
530–615
(275–325)
430–495
(220–260)
700–725
(370–385)
430–475
(220–250)
610–635
(320–335)
Mold Temperature 140–200(60–90)
150–300
(65–148)
140–280
(60–137)
160–240
(70–115)
80–140
(25–60)
300–400
(150–200)
80–140
(25–60)
190–300
(90–150)
Drying Parameters
190 (90)
2–4 Hours
0 .01%–0 .15%
180 (82)
4–5 Hours
0 .10%–0 .20%
275 (135)
3–4 Hours
0 .02%–0 .04%
250 (125)
3–4 Hours
0 .02%
160 (70)
2 Hours
300 (150)
3–4 Hours
0 .10%
160 (70)
2 Hours
280 (135)
2–3 Hours
0 .01%–0 .20%
Nozzle Type General Purpose Nylon or Reverse Taper General Purpose General Purpose General Purpose General Purpose General Purpose General Purpose
Injection Velocity1 2–5 in/sec; 50–127 mm/sec
Injection Pressure 1,000–2,000 psi; 7–14 Mpa
Back Pressure 50–100 psi; 0 .3–0 .7 Mpa
Screw Speed 25–75 RPM
Cushion 0 .125–0 .250 in; 3–6 mm
Screw Compression Ratio2 2 .0:1–2 .5:1
Comments
1 .
Venting Guidelines by Resin
• PC: .001"–.002" depth & .250" width
• PC/PSU: .002"–.003" depth & .250" width
• PES: .003"–.004" depth & .250" width
• PEI: .001"–.003" depth & .250" width
• PP: .001"–.002" depth & .250" width
• ABS: .0015"–.0025" depth & .250" width
• PEEK: .002"–.004" depth & .250" width
FIGURE 40 - Venting Guidelines
Vent Groove
Vent Land
Vent
FIGURE 44 - Venting guidelines
FIGURE 43 - Venting areas
20 Gravi-Tech
CHAPTER 5 | PROCESS OPTIMIZATION
Process optimization ensures a quality process and
minimizes cycle time.
DEFECTS
Design Guide 37
SOURCES
Mold Machine Material Process
Hot spots
Improper cooling
Venting plugged
Leaking check ring
Barrel too hot
Contamination
Too hot
No cushion
Hold pressure too low
Melt temperature
too high
Reduced transfer position
Back pressure too low
RECOMMENDED ADJUSTMENTS
Check venting
Add a flow leader
Insure cushion position
Insure proper screw
recovery
Add a foaming agent Increase hold pressure
Increase hold time
Reduce injection speed
Reduce melt temperature
Reduce mold
temperature
Increase mold
temperature
Sink
Root cause: Material is shrinking away from mold surface .
38 Gravi-Tech
SOURCES
Mold Machine Material Process
Venting impaired
Condensation
Heater band overriding
Wrong screw
configuration
Wet material
Contamination
Injection speed too fast
Residence time too long
Excessive decompression
RECOMMENDED ADJUSTMENTS
Increase gate size
Check mold surface
for condensation
Check for condensation
in feed throat
Check dry material
dew point
Dry material
Increase mold
temperature
Reduce melt temperature
Reduce back pressure
Reduce screw speed
Reduce decompression
Splay
• Silver streaks on part
Root cause: Material degradation
DEFECTS
Design Guide 39
SOURCES
Mold Machine Material Process
Venting impaired Leaking check ring
Heating band burned out
New lot
Contamination
Melt temperature too low
Hold pressure too low
Back pressure too low
Transfer position too high
Injection speed too low
RECOMMENDED ADJUSTMENTS
Clean mold surface
Check vents
Increase gate size
Increase melt
temperature
Increase mold
temperature
Increase hold pressure
Increase hold time
Increase injection speed
Increase back pressure
Decrease transfer
Surface Finish
Root cause: Material is not reproducing the mold surface finish.
40 Gravi-Tech
SOURCES
Mold Machine Material Process
Tooling damage Heater band overriding
Leaking check ring
Contamination
Wet material
Melt temperature
too high
Back pressure too high
No cushion
Pack pressure too high
Hold time too low
RECOMMENDED ADJUSTMENTS
Reduce gate size
Increase cooling in
gate area
Check gate for blockage
Check thermocouples for
continuity
Ensure cushion is
maintained
Dry material Reduce melt temperature
Increase hold pressure
Increase hold time
Reduce back pressure
Increase cooling time
Reduce tip temperature
Gate Vestige
Root cause: Material doesn’t have a clean break at gate .
https://www.avient.com/sites/default/files/2022-03/Asia SEM Healthcare Product Selection Guide %281%29.pdf
PP OVERMOLDING HARDNESS REGULATORY STERILIZATION CHARACTERISTICS
Dynaflex™ G2706 28A
USP Class VI, ISO 10993,
Food contact
EtO
Soft translucent grade,
grippy feel
Dynaflex™ G2711 43A
USP Class VI, ISO 10993,
Food contact
EtO
Highly colorable solution,
grippy feel, low compression set
Versaflex™
CL2242 & CL2250
42A/ 50A
USP Class VI, ISO 10993,
US Food contact
EtO
Clear boilable grades;
ABS, PC bondable
Versaflex™ G2705 N 60A
USP Class VI, ISO 10993,
Food contact
EtO/Steam
High resilience,
low compression set
Versaflex™ HC3810 20A-90A USP Class VI, ISO 10993 EtO General purpose, unfilled
ABS, PC OVERMOLDING HARDNESS REGULATORY STERILIZATION CHARACTERISTICS
Versaflex™ OM1040 40A USP Class VI, ISO 10993 EtO Translucent
Versaflex™ OM3060 60A USP Class VI, ISO 10993 EtO Clear
VERSAFLEX™ CL AND DYNAFLEX™ TPEs
OVERMOLDING FOR
ERGONOMICS
• Adds good tactile surface with soft-touch feel
• Available in a variety of color effects and
textures
• Improves grip, cushion, and comfort
• Enhances functional performance like sealing
properties, vibration damping, oxygen
barrier, and scratch and abrasion resistance
• Reduces assembly costs, good processability
• Offers excellent adhesion to a wide range of
substrates
Applications:
• Glucometers
• Medical tools overmolds
• Injector pens
• Analysis devices
VERSALLOY™ HC & VERSAFLEX™ HC TPEs
SEALING & RESEALING
• Rubbery feel and soft touch
• No coring, good puncture, and
resealability in static stoppers
• Meets low coefficient of friction
requirements in dynamic seals
• Low extractables
• Suitable to overmold onto polyolefins
Applications:
• Sealing and resealing septum
• Seals and sanitary gaskets
• Syringe plungers and tips
MATERIAL DESCRIPTION HARDNESS REGULATORY STERILIZATION CHARACTERISTICS
Versalloy™
HC 9210-45N
45A USP Class VI EtO
Good processability,
smooth surface aesthetics
Versalloy™
HC 9210-55N
55A USP Class VI EtO
Good processability,
smooth surface aesthetics
Versalloy™
HC 9210-70N
70A USP Class VI EtO
Good processability,
smooth surface aesthetics
Versalloy™
HC 9220-43N
43A
USP Class VI,
ISO 10993-4/5
EtO
Extrusion grade,
high temperature resistance
Versaflex™
HC 2110-35N
34A
FDA, USP Class VI,
ISO 10993
Autoclave EtO
radiation
Resealing, elevated comp set
Versaflex™
HC 2110-57B
57A
FDA, USP Class VI,
ISO 10993
Autoclave EtO
radiation
Low stiction
VERSAFLEX™ CL AND DYNAFLEX™ TPEs
HIGH CLARITY
GRADES WITHOUT
PLASTICIZERS
• Water clear grades formulated without
phthalate plasticizers
• Meets medical regulatory USP Class VI and
ISO 10993-4,5
• Food contact and FDA compliant
• Autoclave and radiation stable
• Low extractable
• High clarity (Haze 50 4.1, 100 4.5, 100 4, 70 6, 70
Tensile Modulus (MPa) 2200 2700 2600 2350 1820 1820
Flexural Strength (MPa) 80 90 104 86 68 68
Flexural Modulus (MPa) 2500 2700 2500 2300 1980 1590
HDT: 0.45, 1.8 (MPa) 110, 80 90, 80 100, 89 123, 100 123, 64 100, 70
UL-94 Rating @ 3.0 mm 5VA V-0 5VA V-0 HB V-0
UL-94 Rating @ 1.5 mm V-0 V-0 5VB V-0 HB V-0
UL-94 Rating @ 0.75 mm V-1 V-2 V-0 None None V-2
COMPETITIVE MATERIAL COMPARISON
ENGINEERED POLYMER FORMULATIONS
FOR HEALTHCARE
TRILLIANT™ HC THERMOPLASTICS
The family of Trilliant™ HC high-performance thermoplastics is formulated to meet the growing challenges
of medical devices and equipment.
MATERIAL DESCRIPTION BASE RESIN
Trilliant™ HC2020 Copolyester
Trilliant™ HC8910/8920 Polyketone/ABS blend
Trilliant™ HC2120 Tritan
Trilliant™ HC3120 PC
Trilliant™ HC5210 PP
Trilliant™ HC6010 PA6
Trilliant™ HC6610 PA66
Trilliant™ GRV-NP-110-W PA12
TRILLIANT™ HC THERMOPLASTICS
• Chemically resistant replacement for FR PC/ABS,
FR PC/PET & FR COPE, providing UL 94 Yellow
Card V-0 flame rating at 1.5 mm, V-1 at 0.75 mm
thicknesses for a broad color spectrum
• Outperforms PC/ABS, PC/PET and COPE in
resistance to common disinfectants
• Retains tensile strength after 72-hour exposure
to common hospital disinfectants, and shows
better long-term chemical resistance as
compared to PC blends and COPE
• Exhibits good impact and temperature resistance
• Available in natural grades, standard medical
colors, or custom pre-colored products
Applications:
• Medical device housings
• MRI, X-ray, CT scanner components
• Surgical instruments such as staplers, dissectors,
scissors
• Auto-injector pen
TRILLIANT™ HC
ELECTRICALLY
CONDUCTIVE
FORMULATIONS
• Consistent conductivity ensures repeatable
part performance and minimizes failures
related to inconsistent electrical conductivity
• High flow and easy processing facilitate filling
of thin wall parts and multiple cavity tools,
which enable faster cycle times and lower
per-unit part costs
• Superior durability reduces breakage and
resultant scrap related costs
• Less tendency to flash results in improved
appearance and less fluid retention in or on
the tip, thus driving greater accuracy and less
potential for cross-contamination
• High strength produces parts with greater
stiffness and warp resistance, again
minimizing scrap-related costs
Applications:
• Conductive pipette tips
TEST
TEMS
SPECIFIC
GRAVITY
MELT FLOW
RATE
(230OC,
2.16KG)
TENSILE
STRENGTH
FLEXURAL
STRENGTH
FLEXURAL
MODULUS
IMPACT
STRENGTH
NOTCHED,
IZOD
SURFACE
RESISTIVITY
Method ASTM D-792 ASTM D-1238 ASTM D-638 ASTM D-790 ASTM D-790 ASTM D-256 ASTM D-257
Unit -- g/10min MPa MPa MPa J/m Ohms/sq.
https://www.avient.com/sites/default/files/2021-10/microbial-susceptibility-of-various-polymers-and-evaluation.pdf
From a product-type viewpoint, flexible
polyvinyl chloride (PVC) and poly(urethane)-foam-based
applications have used biocides for decades.[8,9] PVC is
especially vulnerable to attack from fungi and bacteria
due to extensive plasticizer usage in flexible applications.[
10] Poly(urethane) foams are another notable consumer
of biocides because of their porous nature, which pro-
vides an ideal environment for microbes to grow.[11,12]
Therefore, it is not surprising that many applications
based on these two materials have significant usage of
biocides; commonly, oxybisphenoxarsine or lower toxic-
ity alternatives such as zinc pyrithione (ZPT) antimicro-
bials are employed.[10] Specific example applications
include kitchen and bath accessories, swimming pool
liners, carpet backing, sleep solutions like mattresses and
pillows, roofing membranes, and tiles.
https://www.avient.com/sites/default/files/2020-03/polyone-2019-annual-report.pdf
We also completed the divestiture
of Performance Products & Solutions (PP&S) and announced an
agreement to acquire Clariant’s Masterbatch business.
In October, we divested our PP&S segment, which
consisted predominately of the Geon® vinyl
business, for $775 million.
D
O
L
L
A
R
S
*Pro Forma for sale of DSS
2009 2010 2011 2012 2013 2014 2015 2016* 2017* 2018 2018 2019
$2.21
$0.13
$0.68
$0.82
$1.00
$1.31
$1.80
$2.43
$2.06
$1.96
Pro Forma for
sale of PP&S
$1.69
$1.51
12 31 2018 3 31 2019 6 30 2019 9 30 2019 12 31 2019
+32%
2019 POL Stock Price Performance
$
U
.S
.
https://www.avient.com/sites/default/files/2020-05/2.-polyone-ir-presenstation-wells-fargo-industrials-conference.pdf
*** Pro forma for sale of Performance Products and Solutions segment (PP&S).
https://www.avient.com/sites/default/files/2020-05/1.-polyone-ir-presenstation-fermium-research-chemicals-conference.pdf
*** Pro forma for sale of Performance Products and Solutions segment (PP&S).
https://www.avient.com/sites/default/files/2024-04/LubriOne Internally Lubricated Formulations PTFE Free Series Product Bulletin.pdf
KEY CHARACTERISTICS
• Excellent wear resistance
• Reduced friction, heat build-up, noise
& vibration
• Improved processability & surface finish
on parts
• Lower power requirements & low
maintenance
• Reduced tool contamination and corrosion
• Reduction in lubricant migration time
• Design flexibility
• Reduced weight
• Chemically resistant
MARKETS & APPLICATIONS
Ideal for applications in many industries including
transportation, industrial, household, electrical
and electronics including:
• Transportation – Fuel flap axis, interior door
handle axis, gears, seat mechanics, sun-roof
sliding mechanisms, side mirror parts
• Industrial – Conveyor belt gears, pulleys
• Household – Window/door runners, furniture
parts, hinges
• Electrical and electronics – Electrical plug
safety parts, printers, barcode scanners
PRODUCT BULLETIN
EUROPE GRADES
ASIA GRADES
Material Name Base Resin Reinforcing Filler Lubricating Filler
LubriOne LB6000-5024 RS HI natural
PA6
GF10 UHMWPE
Lubrione LB6000-5021 RS S1 GF30 UHMWPE
Lubrione LB6000-5021 RS X2 GF30 UHMWPE
LubriOne LB6000-5019 X1 black GF50 UHMWPE
LubriOne LB6700-5001 RS AF black PA6/PA66 GF50 UHMWPE
LubriOne NN-000/01M black SO
PA66
Unfilled MoS2
LubriOne REC LB6600-5030 RS grey GF33 Graphite
LubriOne LB3300-5010 RS natural
PBT
GF20 UHMWPE
LubriOne LB3300-5005 RS natural MI20 UHMWPE
LubriOne REC LB3220-5001 RS C natural X1 PC GF10 UHMWPE
LubriOne LB8900-5010 GP grey
PKE
Unfilled Graphite
LubriOne LB8900-5006 RS PE natural GF20 UHMWPE
LubriOne LB8900-5004 RS PE natural GF30 UHMWPE
LubriOne LB4200-5022 black
POM
Unfilled MoS2
LubriOne LB4200-5023 natural Unfilled UHMWPE
LubriOne LB9200-5012 RS PE natural PPS GF30 UHMWPE
Material Name Base Resin Reinforcing Filler Lubricating Filler
LubriOne LB6600-8056 LB BK001
PA66
Unfilled LDPE
LubriOne LB6600-8054 RS BK001 CF30 LDPE
LubriOne LB6600-8052 RS BK001 GF30 LDPE
LubriOne LB4200-8032 RS NC001
POM
GF30 LDPE
LubriOne LB4200-8030 AR NC001 AF10 LDPE
LubriOne LB4200-8026 LB BK001 Unfilled LDPE+HDPE
LubriOne LB3200-8022 LB BK001
PC
Unfilled UHMWHDPE
LubriOne LB3200-8021 RS BK001 GF30 UHMWHDPE
LubriOne LB7600-8008 RS BK001 PPO GF20 UHMWHDPE
Copyright © 2024, Avient Corporation.
https://www.avient.com/sites/default/files/2021-09/olefins-brochure.pdf
POLYOLEFINS
ALIGNING WITH
SUSTAINABILITY GOALS
POLYOLEFINS
ARE EVERYWHERE
Polyethylene (PE) and polypropylene (PP) are among
the most popular plastics in the world.
https://www.avient.com/sites/default/files/2022-12/Mevopur Healthcare Colorants and Formulations for Needle Hubs Application Bulletin.pdf
Available
in opaque or transparent form based on PP resins,
either as a concentrate or pre-colored formulation,
the colors are standardized to RAL and Pantone
color systems.